You can work out TDC on #1 pretty easily even with no reference marks.
Make a pointer up out of stiff wire and attach it securely to the engine so it points at the harmonic balancer. This will be your reference for TDC in the future, so make it permanent and make it strong
Take out #1 spark plug and wind the motor over by hand until you can see the piston in the bore, but before it comes to the top of the stroke. Take a bit of your stiff wire and poke it down the near side of the bore - make sure it's touching the side - until it touches the piston, and take close note of the depth - make a reference mark on it with a knife or something sharp.
At this point, mark the harmonic balancer where the pointer is pointing.
Now, continue to wind the motor beyond TDC and keep measuring the depth of the piston with your wire in the plug hole. Once it goes back down to your reference mark, stop and make another mark on the harmonic balancer.
Now measure the distance between the two marks on the balancer, and exactly half way between is top dead centre, spot on.
Make sure you do this with the dizzy rotor pointing towards plug #1 and not #4, otherwise you've found TDC on the exhaust stroke, not the compression stroke.
[edit] Doc beat me, even if we have slightly different methods - his is probably easier
